This
situation is referred to asPseudo-first order kinetics, and is confirmed when First order kinetics are observed for the drug disappearance.
Also applies for reactions involvingacid (H3O+)orbase(OH-)when high concentrations or buffers are used in the reaction solution thereby maintaining the reagent at constant
concentration.
Sometimes, a reaction can be observed to
follow ZERO order kinetics
-d [ D ] / dt=k0
eg,a sparingly soluble
drug undergoes degradation in solution - in the presence of solid drug, the solution concentration
remains constant at the
saturation solubility.